Section MC 1103: Refrigeration System Classification
1103.1 Refrigerant classification.
Refrigerants shall be classified in accordance with ASHRAE 34 as listed in Table 1103.1.
Table 1103.1
Refrigerant Data and Safety Classifications a
Refrigerant Number Chemical Name Chemical Formula OEL d ppm v/v Safety c Group RCL
(ppm v/v) (g/m3) Ib/Mcf
Methane Series
11 b trichlorofluoromethane CCl3F C1000 A1 1,100 6.2 .39
12 b dichlorodifluoromethane CCl2F2 1,000 A1 18,000 90 5.6
13 b chlorotrifluoromethane CClF3 1,000 A1 - - -
13B1 b bromotrifluoromethane CBrF3 1,000 A1 - - -
14 tetrafluoromethane (carbon tetrafluoride) CF4 1,000 A1 110,000 400 25
21 dichlorofluoromethane CHCl2F - B1 - - -
22 chlorodifluoromethane CHClF2 1,000 A1 59,000 210 13
23 trifluoromethane CHF3 1,000 A1 41,000 120 7.3
30 dichloromethane (methylene chloride) CH2Cl2 - B2 - - -
32 difluoromethane (methylene fluoride) CH2F2 1,000 A2L 36,000 77 4.8
40 chloromethane (methyl chloride) CH3Cl - B2 - - -
50 methane CH4 1,000 A3 - - -
Ethane Series
113 b 1,1,2-trichloro-1,2,2-trifluoroethane CCl2FCClF2 1,000 A1 2,600 20 1.2
114 b 1,2-dichloro-1,1,2,2- tetrafluoroethane CClF2CClF2 1,000 A1 20,000 140 8.7
115 b chloropentafluoroethane CClF2CF3 1,000 A1 120,000 760 47
116 hexafluoroethane CF3CF3 1,000 A1 97,000 550 34
123 2,2-dichloro-1,1,1,-trifluoroethane CHCl2CF3 50 B1 9,100 57 3.5
124 2-chloro-1,1,1,2-tetrafluoroethane CHClFCF3 1,000 A1 10,000 56 3.5
125 pentafluoroethane CHF2CF3 1,000 A1 75,000 370 23
134 a 1,1,1,2-tetrafluoroethane CH2FCF3 1,000 A1 50,000 210 13
142 b 1-chloro-1, 1-difluoroethane CH3CClF2 1,000 A2 20,000 83 5.1
143 a 1,1,1-trifluoroethane CH3CF3 1,000 A2L 21,000 70 4.5
152 a 1,1-difluoroethane CH3CHF2 1,000 A2 12,000 32 2.0
170 ethane CH3CH3 1,000 A3 7,000 8.7 0.54
Ethers
E170 methoxymethane (dimethyl ether) CH3OCH3 1,000 A3 8,500 16 1.0
Propane
218 octafluoropropane CF3,CF2CF3 1,000 A1 90,000 690 43
227 ea 1,1,1,2,3,3,3-heptafluoropropane CF3CHFCF3 1,000 A1 84,000 580 36
236 fa 1,1,1,3,3,3-hexafluoropropane CF3CH2CF3 1,000 A1 55,000 340 21
245 fa 1,1,1,3,3-pentafluoropropane CHF2CH2CF3 300 B1 34,000 190 12
290 propane CH3CH2CH3 1,000 A3 5,300 9.5 0.56
Cyclic Organic Compounds
C318 octafluorocyclobutane -(CF2)4- 1,000 A1 80,000 660 41
Miscellaneous Organic Compounds Hydrocarbons
600 butane CH3CH2CH2CH3 1,000 A3 - - .51
600 a 2-methylpropane (isobutane) CH(CH3)2CH3 1,000 A3 4,000 9.6 .59
601 pentane CH3CH2CH2CH2CH3 600 A3 1,000 2.9 .18
601 a 2-methylbutane (isopentane) (CH3)2CHCH2CH3 600 A3 1,000 2.9 .18
611 methyl formate HCOOCH3 100 B2 - - -
Inorganic Compounds
702 hydrogen H2 - A3 - - -
704 helium He - A1 - - -
717 ammonia NH3 25 B2L 320 0.22 .014
718 water H2O - A1 - - -
720 neon Ne - A1 - - -
728 nitrogen N2 - A1 - - -
740 argon Ar - A1 - - -
744 carbon dioxide CO2 5000 A1 40,000 72 4.5
764 sulfur dioxide SO2 - B1 - - -
Unsaturated Organic Compounds
1150 ethene (ethylene) CH2=CH2 200 A3 - - -
1234yf 2,3,3,3-tetrafluoro-1-propene CF3CF=CH2 500 A2L 16,000 75 4.7
1234ze(E) trans-1,3,3,3-tetrafluoro-1-propene CF3CH=CHF 800 A2L 16,000 75 4.7
1270 propene (propylene) CH3CH=CH2 500 A3 1,000 1.7 .1
Zeotropes (Refrigerant Blends)
400 (50%/50%) b R-12/114 (50.0/50.0) 1,000 A1 28,000 160 10
400 (60%/40%) b R-12/114 (60.0/40.0) 1,000 A1 30,000 170 11
401A R-22/152a/124 (53.0/13.0/34.0) (±2.0/+0.5, -1.5;/±1.0) 1,000 A1 27,000 110 6.6
401B R-22,/152a/124 (61.0/11.0/28.0) (±2.0/+0.5, -1.5/±1.0) 1,000 A1 30,000 120 7.2
401C R-22,/152a/124 (33.0/15.0/52.0) (±2.0/+0.5, -1.5/±1.0) 1,000 A1 20,000 84 5.2
402A R-125/290/22 (60.0/2.0/38.0) (±2.0/+0.1, -1.0/±2.0) 1,000 A1 33,000 140 8.5
402B R-125/290/22 (38.0/2.0/60.0) (±2.0/+0.1, -1.0/±2.0) 1,000 A1 63,000 240 15
403A R-290/22/218 (5.0/75.0/20.0) (+.2, -2.0/±2.0/±2.0) 1,000 A2 33,000 120 7.6
403B R-290/22/218 (5.0/56.0/39.0) (+.2, -2.0/±2.0/±2.0) 1,000 A1 70,000 290 18
404A R-125/143a/134a (44.0/52.0/4.0) (±2.0/±1.0/±2.0) 1,000 A1 130,000 500 31
406A R-22/600a/142b (55.0/4.0/41.0) (±2.0/±1.0/±1.0) 1,000 A2 21,000 25 4.7
407A R-32/125/134a (20.0/40.0/40.0) (±2.0/±2.0/±2.0) 1,000 A1 83,000 300 19
407B R-32/125/134a (10.0/70.0/20.0) (±2.0/±2.0/±2.0) 1,000 A1 79,000 330 21
407C R-32/125/134a (23.0/25.0/52.0) (±2.0/±2.0/±2.0) 1,000 A1 81,000 290 18
407D R-32/125/134a (15.0/15.0/70.0) (±2.0/±2.0/±2.0) 1,000 A1 68,000 250 16
407E R-32/125/134a (25.0/15.0/60.0) (±2.0/±2.0/±2.0) 1,000 A1 80,000 280 17
407F R-32/125/134a (30.0/30.0/40.0) (±2.0/±2.0/±2.0) 1,000 A1 95,000 320 20
408A R-125/143a/22 (7.0/46.0/47.0) (±2.0/±1.0/±2.0) 1,000 A1 95,000 110 21
409A R-22/124/142b (60.0/25.0/15.0) (±2.0/±2.0/±1.0) 1,000 A1 29,000 120 7.1
409B R-22/124/142b (65.0/25.0/10.0) (±2.0/±2.0/±1.0) 1,000 A1 30,000 390 7.3
410A R-32/125 (50.0/50.0) (+0.5, -1.5/+1.5, -0.5) 1,000 A1 140,000 420 26
410B R-32/125 (45.0/55.0) (±1.0/±1.0) 1,000 A1 140,000 430 27
411A R-1270/22/152a(1.5/87.5/11.0) (+0.0, -1.0/+2.0,-0.0/+0.0, -1.0) 990 A2 14,000 46 2.9
411B R-1270/22/152a(3.0/94.0/3.0) (+0.0, -1.0/+2.0,-0.0/+0.0, -1.0) 980 A2 13,000 45 2.8
412A R-22/218/142b (70.0/5.0/25.0) (±2.0/±2.0/±1.0) 1,000 A2 22,000 82 5.1
413A R-218/134a/600a (9.0/88.0/3.0) ±1.0/±2.0/+0.0,-1.0) 1,000 A2 22,000 95 5.8
414A R-22/124/600a/142b(51.0/28.5/4.0/16.5) (±2.0/±2.0/±0.5 /+0.5, -1.0) 1,000 A1 26,000 100 6.4
414B R-22/124/600a/142b(50.0/39.0/1.5/9.5) (±2.0/±2.0/±0.5 /+0.5, -1.0) 1,000 A1 23,000 95 6.0
415A R-22/152a (82.0/18.0) (±1.0/±1.0) 1,000 A2 57,000 190 12
415B R-22/152a (25.0/75.0) (±1.0/±1.0) 1,000 A2 52,000 120 9.3
416A R-134a/124/600(59.0/39.5/1.5) (+0.5, -1.0/+1.0,-0.5/+1.0, -0.2) 1,000 A1 14,000 62 3.9
417A R-125/134a/600 (46.6/50.0/3.4) (±1.1/±1.0/+0.1,-0.4) 1,000 A1 13,000 56 3.5
417B R-125/134a/600 (79.0/18.3/2.7) (±1.0/±1.0/+0.1,-0.5) 1,000 A1 15,000 70 4.3
418A R-290/22/152a (1.5/96.0/2.5 (±0.5/±1.0/±0.5) 1,000 A2 59,000 200 13
419A R-125/134a/E170 (77.0/19.0/4.0) (1.0/1.0/1.0) 1,000 A2 70,000 310 19
420A R-134a/142b (88.0/12.0) (+1.0,-0.0/+0.0,-1.0) 1,000 A1 45,000 190 12
421A R-125/134a (58.0/42.0) (±1.0/±1.0) 1,000 A1 61,000 280 17
421B R-125/134a (85.0/15.0) (±1.0/±1.0) 1,000 A1 69,000 330 21
422A R-125/134a/600a (55.0/42.0/3.0) (±1.0/±1.0/+0.1,-0.4) 1,000 A1 63,000 290 18
422B R-125/134a/600a (82.0/15.0/3.0) (±1.0/±1.0/+0.1,-0.5) 1,000 A1 56,000 250 16
422C R-125/134a/600a (82.0/15.0/3.0) (±1.0/±1.0/+0.1,-0.5) 1,000 A1 62,000 290 18
422D R-125/134a/600a(65.1/31.5/3.4) (+0.9,-1.1/±1.0/+0.1,-0.4) 1,000 A1 58,000 260 16
423A R-134a/227ea (52.5/47.5) (±1.0/±1.0) 1,000 A1 59,000 310 19
424A R-125/134a/600a/600/601a(50.5/47.0/0.9/1.0/0.6) (±1.0/±1.0/+0.1,-0.2/+0.1, +0.2/+0.1,-0.2) 970 A1 23,000 100 6.2
425A R-32/134a/227ea (18.5/69.5/12.0) (±0.5/±0.5/±0.5) 1,000 A1 72,000 260 16
426A R-125/134a/600/601a(5.1/93.0/1.3/0.6) (±1.0/±1.0/+0.1,-0.2/+0.1, -0.2) 990 A1 20,000 83 5.2
427A R-32/125/143a/134a(15.0/25.0/10.0/50.0) (±2.0/±2.0/±2.0/;±2.0) 1,000 A1 79,000 290 18
428A R-125/143a/290/600a(77.5/20.0/0.6/1.9) (±1.0/±1.0/+0.1,-0.2/+0.1, -0.2) 1,000 A1 83,000 370 23
429A R-E170/152a/600a(60.0/10.0/30.0) (±1.0/±1.0/±1.0) 1,000 A3 6,300 13 .81
430A R-152a/600a (76.0/24.0) (±1.0/±1.0) 1,000 A3 8,000 21 1.3
431A R-290/152a (71.0/29.0) (±1.0/±1.0) 1,000 A3 5,500 11 .69
432A R-1270/E170 (80.0/20.0) (±1.0/±1.0) 710 A3 1,200 2.1 .13
433A R-1270/290 (30.0/70.0) (±1.0/±1.0) 880 A3 3,100 5.5 .34
433B R-1270/290 (5.0/95.0) (±1.0/±1.0) 950 A3 4,500 8.1 .51
433C R-1270/290 (25.0/75.0) (±1.0/±1.0) 790 A3 3,600 6.6 .41
434A R-125/143a/134a/600a(63.2/18.0/16.0/2.8) (±1.0/±1.0±1.0/+0.1,-0.2) 1,000 A1 73,000 320 20
435A R-E170/152a (80.0/20.0) (±1.0/±1.0) 1,000 A3 8,500 17 1.1
436A R-290/600a (56.0/44.0) (±1.0/±1.0) 1,000 A3 4,000 8.1 .5
436B R-290/600a (52.0/48.0) (±1.0/±1.0) 1,000 A3 4,000 8.1 .5
437A R-125/134a/600/601(19.5/78.5/1.4/0.6) (+0.5,-1.8/+1.5,-0.7/+0.1,-0.2/+0.1,-0.2) 990 A1 19,000 81 5.0
438A R-32/125/134a/600/601a(8.5/45.0/44.2/1.7/0.6) (+0.5,-1.5/±1.5/±1.5/+0.1,-0.2/+0.1,-0.2) 990 A1 20,000 79 4.9
439A R-32/125/600a(50.0/47.0/3.0) (±1.0/±1.0/±0.5) 990 A2 26,000 76 4.7
440A R-290/134a/152a(0.6/1.6/97.8) (±1.0/±0.6/±0.5) 1,000 A2 12,000 31 1.9
441A R-179/290/600a/600(3.1/54.8/6.0/36.1) (±0.3/±2.0/±0.6/±2.0) 1,000 A3 3,200 6.3 .39
Azeotropes (Refrigerant Blends)
500 b R-12/152a (73.8/26.2) - 1,000 A1 30,000 120 7.6
501 b R-22/12 (75.0/25.0) - 1,000 A1 54,000 210 13
502 b R-22/115 (48.8/51.2) - 1,000 A1 73,000 330 21
504 R-32/115 (48.2/51.8) - 1,000 - 140,000 450 28
507A R-125/143a (50.0/50.0) - 1,000 A1 130,000 520 32
508A R-23/116 (39.0/61.0) - 1,000 A1 55,000 220 14
508B R-23/116 (46.0/54.0) - 1,000 A1 52,000 200 13
509A R-22/218 (44.0/56.0) - 1,000 A1 75,000 390 24
510A R-E170/600a (88.0/12.0) (±0.5/±0.5) 1,000 A3 7,300 14 .87
511A R-290/E170 (95.0,5.0) (±1.0/±1.0) 1,000 A3 5,300 9.5 .59
For SI: 1 pound = 0.454 kg, 1 cubic foot = 0.0283 m3.
a. Data based on ASHRAE 34 including Addenda a through o. For more complete data, see ASHRAE 34 and Addenda. Use of Addenda issued after Addendum o is subject to approval as set forth in Section 1102.2.
b. Class I ozone depleting refrigerant. Not permitted for new installations.
c. Refrigerants in Safety Group "A2L" shall comply with rules of the department. Refrigerants in Safety Group "B2L" shall comply with all applicable requirements for "B2" refrigerants.
d. OCCUPATIONAL EXPOSURE LIMIT (OEL). The time-weighted average (TWA) concentration for a normal 8-hour workday and a 40-hour workweek to which nearly all workers can be repeatedly exposed without adverse effect, based on the OSHA PEL, ACGIH TLV-TWA, AIHA WEEL, or consistent value.
(Am. L.L. 2023/077, 6/11/2023, eff. 6/11/2023)
Editor's note: For related unconsolidated provisions, see Appendix A at L.L. 2023/077.
1103.2 Occupancy classification.
Locations of refrigerating systems are described by occupancy classifications that consider the ability of people to respond to potential exposure to refrigerants. Where equipment or appliances, other than piping, are located outside a building and within 20 feet (6096 mm) of any building opening, such equipment or appliances shall be governed by the occupancy classification of the building. Occupancy classifications of buildings shall be in accordance with the building classifications in the New York City Building Code.
1. Institutional occupancy shall include Occupancy Groups I-1, I-2, I-3 and I-4.
2. Public assembly occupancy shall include Occupancy Groups A-1, A-2, A-3, A-4, A-5 and E.
3. Residential occupancy shall include Occupancy Groups R-1, R-2 and R-3.
4. Commercial occupancy shall include Occupancy Groups M and B, except Occupancy Group M with retail stores having an occupant load of more than 100 persons on any floor other than street level.
5. Large mercantile occupancy shall include Occupancy Group M with retail stores having an occupant load of more than 100 persons on any floor other than street level.
6. Industrial occupancy shall include Occupancy Groups F-1, F-2, H-1, H-2, H-3, H-4, H-5, S-1 and S-2.
7. Mixed occupancy occurs where two or more occupancies are located within the same building. Where each occupancy is isolated from the rest of the building by tight walls, floors and ceilings and by self-closing doors, the requirements for each occupancy shall apply to its portion of the building. Where the various occupancies are not so isolated, the occupancy having the most stringent requirements shall be the governing occupancy.
1103.3 System classification.
Refrigeration systems shall be classified according to the degree of probability that refrigerant leaked from a failed connection, seal or component could enter an occupied area. The distinction is based on the basic design or location of the components.
1103.3.1 Low-probability systems.
Double-indirect open-spray systems, indirect closed systems and indirect-vented closed systems shall be classified as low-probability systems, provided that all refrigerant-containing piping and fittings are isolated when the quantities in Table 1103.1 are exceeded.
1103.3.2 High-probability systems.
Direct systems and indirect open-spray systems shall be classified as high-probability systems.
Exception: An indirect open-spray system shall not be required to be classified as a high-probability system if the pressure of the secondary coolant is at all times (operating and standby) greater than the pressure of the refrigerant.